Article Dans Une Revue Molecules Année : 2025

Magnetite-Doped Activated Carbon Beads and Powder Derived from Chitosan for Adsorption of Emerging Contaminants in Drinkable Water

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Activated carbon beads, some of which contain Fe3O4 nanoparticles or graphene oxide, were synthesized by thermal activation (700 °C) of chitosan hydrogel beads. Materials showed a multiporous scale (micro/meso/macro) and BET specific surface areas in the 260–572 m2.g−1 range. The adsorption kinetics of beads and powders resulting from their grinding were studied for a mixture of six micropollutants (bisphenol A, carbofuran, carbamazepine, diclofenac, dimethoate and imidacloprid) dissolved in spring water. While the adsorption kinetics on the beads (pH 7.3, 25 °C, 10–100 µg.L−1) are slow (equilibrium time > 24 h), the powdered samples are more efficient: for an initial concentration of 50 μg.L−1 of each pollutant (0.1 g.L−1 of adsorbent), 50 to 99% of the micropollutants introduced into the solution were removed after 4 h of contact time. Depending on the pollutant nature, the adsorption isotherms (0.2–40 μg.L−1) studied for an activated carbon powder containing Fe3O4 (1 mass %) are either of Langmuir or Freundlich type, or they follow Henry’s law and are related to the different properties of the molecules.

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hal-05374538 , version 1 (25-11-2025)

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Nirav Raval, Laurence Reinert, Laurent Duclaux, Nathalie Cottin, Noriko Yoshizawa, et al.. Magnetite-Doped Activated Carbon Beads and Powder Derived from Chitosan for Adsorption of Emerging Contaminants in Drinkable Water. Molecules, 2025, 30 (22), pp.4443. ⟨10.3390/molecules30224443⟩. ⟨hal-05374538⟩
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