Correlating Crystallinity and Electrical Conductivity in Gamma-Irradiated PTFE - IUT Paul Sabatier
Communication Dans Un Congrès Année : 2024

Correlating Crystallinity and Electrical Conductivity in Gamma-Irradiated PTFE

Résumé

Exposing polytetrafluoroethylene (PTFE) to irradiation brings about significant alterations in both its crystallinity and conductivity. The primary objective of this study is to investigate the connection, if any, between crystallinity, a structural feature, and electrical conductivity, which represents a macroscopic property. This was accomplished by subjecting PTFE to varying doses of γ-rays, reaching up to 200 kGy. Various physicochemical characterizations were conducted to elucidate the impact of irradiation on dielectric properties. We show that irradiation produces chain scission and oxidized groups at chain ends. The material becomes more crystallizable after irradiation whereas the increase in conductivity would result from transport due to oxidized groups and short chain formation.

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Dates et versions

hal-04690593 , version 1 (06-09-2024)

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Ali Mezouar, Nadia Saidi-Amroun, Virginie Griseri, Gilbert Teyssèdre, Mohamed Saidi. Correlating Crystallinity and Electrical Conductivity in Gamma-Irradiated PTFE. 2024 IEEE 5th International Conference on Dielectrics (ICD), Jun 2024, Toulouse, France. pp.1-4, ⟨10.1109/ICD59037.2024.10613047⟩. ⟨hal-04690593⟩
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